The 2015 CMA Awards had country's best new artist team up with one of pop's biggest superstars. Chris Stapleton teamed up with Justin Timberlake on stage for two songs: "Tennesee Whiskey," as widely heard from honky tonk king George Jones; and "Drink You Away," off Justin's The 20/20 Experience.

Audience members like Keith Urban and Jewel might not have been used to seeing Chris in the spotlight (past credits include Kenny Chesney and Miranda Lambert) or heard "Drink You Away," where Justin shows his Memphis roots. But they surely recognized that this pop-country duet was one for the books. Watch below.